Navigation

22BBI392 - Physical Chemistry II

Course specification
Course titlePhysical Chemistry II
Acronym22BBI392
Study programmeBiochemical Engineering and Biotechnology
Module
Lecturer (for classes)
Lecturer/Associate (for practice)
    Lecturer/Associate (for OTC)
      ESPB5.0Status
      ConditionGeneral Chemistry II, Mathematics II, Technical Physics II (attendance), Physical Chemistry I (exam)Облик условљености
      The goalPhysical Chemistry II course aims to provide the knowledge of coloidal systems; to improve the understanding of the formal chemical kinetics through study of the complex reactions and their molecular background, and to provide the basic knowledge for understanding of electrochemical reactions as unique class of heterogeneous chemical reactions.
      The outcomeStudent would be able to understand properties of the phase boundaries and acquired knowledge on different colloid system which would enable them to have the bases for understanding of specific and practical technologies lately discussed in practical undergraduate and graduate courses. They would have understood the models of complex chemical reactions and the influence of various parameters on the reaction rate and adopted basic principles underlying catalytic processes. They would be able to distinguish between chemical and electrochemical reactions and to adopt basis for understanding of electrochemical reactions in equilibrium and non-equilibrium conditions.
      Contents
      Contents of lectures• Colloids (classification of colloids, colloid dispersions, surfactants and associative colloids, macromolecular colloids, preparation and purification of colloidal systems, determination of particles size and distribution of sizes of particles, kinetic properties of colloidal system, surface phenomena, optical properties of colloidal system, electrical properties of the phase boundaries, electrokinetic phenomena, rheological properties of colloidal system, stability and coagulation of colloidal system, emulsions,gels) • Electrochemistry (ions in the solution, ionic transport, membrane potential active and passive transport, electrochemical half-reaction, equilibrium electrochemistry and Nernst equation, classification of electrodes, electrochemical thermodynamics and classification of electrochemical systems, biochemical standard state) • Chemical kinetics (kinetics of the complex chemical reactions-parallel, consecutive, chain reactions, reactions in solutions, mechanisms of complex reactions, catalysis – homogeneous, heterogeneous)
      Contents of exercises• Gibbs adsorption isotherm • Electro-kinetic potential of colloid particles • Determination of the tixotrophy coefficient using rotational viscometer • Standard electrode potentials and potentiometric titration • Specific and general acid-base catalysis
      Literature
      1. P.Atkins, J. de Paula, ЕLEMENTS OF PHYSICAL CHEMISTRY, Oxford University Press, 2005.
      2. P.C. Hiemenz, Principles of Colloid and Surface Chemistry, Marcel Dekker, Inc., New York, 1977;
      3. Lj. Vračar i drugi, EKSPERIMENTALNA FIZIČKA HEMIJA, TMF, Beograd, 2010. (Original title)
      4. D. Ovcin i drugi, FIZIČKA HEMIJA – ZBIRKA ZADATAKA, TMF, Beograd, 2004. (Original title)
      5. P.Atkins, J. de Paula, ELEMENTS OF PHYSICAL CHEMISTRY, Oxford University Press, 2005. (Original title)
      Number of hours per week during the semester/trimester/year
      LecturesExercisesOTCStudy and ResearchOther classes
      31
      Methods of teachingLectures, theoretical and numerical exercises. Laboratory experiments.
      Knowledge score (maximum points 100)
      Pre obligationsPointsFinal examPoints
      Activites during lecturesTest paper55
      Practical lessons15Oral examination
      Projects
      Colloquia30
      Seminars