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22DVKT - Advanced Chemical Engineering Thermodynamics

Course specification
Course titleAdvanced Chemical Engineering Thermodynamics
Acronym22DVKT
Study programmeBiochemical Engineering and Biotechnology,Chemical Engineering
Module
Lecturer (for classes)
Lecturer/Associate (for practice)
    Lecturer/Associate (for OTC)
      ESPB6.0Status
      Condition-Облик условљености
      The goalThe aim of the course is to make adequate relations between molecular and classical thermodynamics, using the results obtained by the statistical thermodynamic. In order to have appropriate description of the solution behavior, selection of a theoretical model will be described Phase equilibria, relevant to the chemical, polymer, pharmaceutical and biochemical engineering and ecology will be modeled.
      The outcomeAfter this course students will be able: (1) to analyze complex thermodynamic process, (2) to solve thermodynamic problems using several/different types of approaches (classical and molecular), (3) to adapt projects to new or modified thermodynamic conditions (4) to gain competencies and skills needed to work in scientific research team.
      Contents
      Contents of lectures• Phase equilibria models. (Phase diagrams. Vapour-liquid equilibrium at low pressures. Vapour-liquid equilibrium at moderate and high pressures: calculations by an equation of state and by - method. Liquid-liquid equilibrium.) diagrams. •The fugacity of gaseous mixtures (virial coefficients and potentials). Fugacity of the liquid mixture (Excess functions for binary and multicomponent mixtures Wilson, NRTL, UNIQUAC equation). Excess functions and partial miscibility. Predicting of the activity coefficients: UNIFAC equation. • Models and theories of the solution (van Laar, Scatchard-Hildebrand theory, two-fluid theory, etc). • Polymers: Flory-Huggins theory; equation of state for polymer solutions (Prigogine-Flory-Patterson theory). • Thermodynamics of emulsions (thermodynamic theory of emulsions formation and their stability). • Solubility of gases and solids in liquids. • Phase equilibria at high pressure (liquid-liquid equilibria, the gas-liquid equilibria, phase equilibria calculation using equations of state, equilibrium phase calculation using chemical theory). • Molecular simulation.
      Contents of exercises
      Literature
      1. Đorđević, B., Kijevčanin, M., Radović, I., Šerbanović, S., Hemijsko-inženjerska termodinamika, TMF, 2013.
      2. Prausnitz, J.M., Lichtenthaler, R.N., de Azevedo, E.G. Molecular Thermodynamics of Fluid-Phase Equilibria, 3rd ed., Prentice Hall, New Jersey, 1998
      3. Poling, B.E., Prausnitz, J.M., O'Connell, J.P., The Properties of Gases and Liquids,5th ed., McGraw-Hill, New York, 2001
      4. J. Smith, H. Van Ness, M. Abbott, M. Swihart, Introduction to Chemical Engineering Thermodynamics, Mcraw-Hill, 2018
      Number of hours per week during the semester/trimester/year
      LecturesExercisesOTCStudy and ResearchOther classes
      3
      Methods of teachingTheoretical and practical lectures.
      Knowledge score (maximum points 100)
      Pre obligationsPointsFinal examPoints
      Activites during lecturesTest paper
      Practical lessons40Oral examination
      Projects
      Colloquia
      Seminars