22HPI3 - Chemical Engineering Thermodynamics

Course specification
Course title		Chemical Engineering Thermodynamics
Acronym		22HPI3
Study programme
Module
Lecturer (for classes)		prof. dr Mirjana Kijevčanin prof. dr Ivona Radović
Lecturer/Associate (for practice)		prof. dr Mirjana Kijevčanin prof. dr Ivona Radović
Lecturer/Associate (for OTC)
ESPB		5.0	Status
Condition		Thermodynamics	Облик условљености
The goal		Comprehension of thermodynamic properties calculations necessary for the analysis and design of the industrial process equipment.
The outcome		Students will learn about thermodynamic properties of pure substances or multicomponent mixtures: gas phase, liquid mixtures, phase equilibria. Application of fundamental equations for correlation and prediction of thermodynamic properties of pure substances, simple and complex mixtures of non polar, weakly polar and highly polar compounds, as well as of asymmetric mixtures containing associates and solvates.
Contents
Contents of lectures		Thermodynamic properties of pure fluids. Two and three-parameter corresponding state. Virial equation of state. Cubic equations of state. Determination of thermodynamic properties of pure systems. (Fundamental properties relations. Maxwell equations. Residual properties. Calculation of thermodynamic properties of pure fluids: enthalpy, entropy, chemical potential, fugacity and fugacity coefficient.) Determination of thermodynamic properties in multicomponent systems. (Application of virial and cubic equations of state for the calculation of thermodynamic properties of mixtures. Mixing rules. Fundamental thermodynamic relations. Partial properties. Ideal solutions. Chemical potential. Fugacity and fugacity coefficient in mixtures.) Excess functions and solution theory. (Activity. Activity coefficient. Activity coefficient models. Solution theory.) Phase equilibria models. (Phase diagrams. Vapour-liquid equilibrium at low pressures. Vapour-liquid equilibrium at moderate and high pressures: calculations by an equation of state and by - method. Liquid-liquid equilibrium.) diagrams. Equilibrium in reacting systems. (Gibbs phase rule. Criteria for reaction equilibrium and equilibrium constant. Pressure and temperature effect on equilibrium constant. Multireaction equilibria. )
Contents of exercises		Examples that follow the theoretical classes. Application of computer programs.
Literature
"Đorđević, B., Kijevčanin, M., Radović, I., Šerbanović, S., Hemijsko-inženjerska termodinamika, TMF, 2013." (Original title) "J. Smith, H. Van Ness, M. Abbott, M. Swihart, Introduction to Chemical Engineering Thermodynamics, Mcraw-Hill, 2018" (Original title) "B.E. Poling, J.M. Prausnitz, J.P. O'Connell, The Properties of Gases and Liquids, McGraw-Hill, New York, 2001. " (Original title)
Number of hours per week during the semester/trimester/year
Lectures	Exercises	OTC	Study and Research	Other classes
3	2
Methods of teaching		Theoretical and practical lectures.
Knowledge score (maximum points 100)
Pre obligations		Points	Final exam	Points
Activites during lectures			Test paper	30
Practical lessons		20	Oral examination
Projects
Colloquia		40
Seminars